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Education:
Ph.D. in Inorganic Chemistry, University of Minnesota, Minneapolis MN (July 2007).
Graduate Research Advisor: Prof. William B. Tolman "Application of N-Donor Ligated Copper Complexes in Dioxygen Activation and the Synthesis of Copper-Sulfur Centers Relevant to Biology.”
B.A. in Secondary Science Education (suma cum laude), University of Wyoming, Laramie WY (May 2001).
B.S. in Chemical Engineering (suma cum laude), North Carolina State University, Raleigh NC (May 1995).
Publications:
[1] Sarangi, R.; York, J. T.; Helton, M. E.; Fujisawa, K.; Karlin, K. D.; Tolman, W. B.; Hodgson, K. O.; Hedman, B.; Solomon, E. I. “X-Ray Absorption Spectroscopic and Theoretical Studies on (L)2[Cu2(S2)n]2+ Complexes: Disulfide versus Disulfide( 1-).” Bonding. Journal of the American Chemical Society 2008, 130, 676-686.
[2] Bar-Nahum, I.; York, J. T.; Young, V. G., Jr.; Tolman, W. B. “Novel Reactivity of Side-On (Disulfido)Dicopper Complexes Supported by Bi- and Tridentate N-Donors: Impact of Axial Coordination.” Angewandte Chemie, International Edition 2008, 47, 533-536.
[3] York, J. T.; Bar-Nahum, I.; Tolman, W. B. “Copper-Sulfur Complexes Supported by N-Donor Ligands: Towards Models of the CuZ Site in Nitrous Oxide Reductase.” Inorganica Chimica Acta (Special issue in honor of Prof. Edward Solomon), 2008, 361, 885-893.
[4] York, J. T.; Bar-Nahum, I.; Tolman, W. B. “Structural Diversity in Copper-Sulfur Chemistry: Synthesis of Novel Cu-S Clusters through Metathesis Reactions.” Inorganic Chemistry 2007, 46, 8105-8107.
[5] York, J. T.; Llobet, A.; Cramer, C. J.; Tolman, W. B. “Heterobimetallic Dioxygen Activation: Synthesis and Reactivity of Mixed Cu-Pd and Cu-Pt Bis(m-oxo) Complexes.” Journal of the American Chemical Society 2007, 129, 7990-7999.
[6] Brown, E. C.; Bar-Nahum, I.; York, J. T.; Aboelella, N. W.; Tolman, W. B. “Ligand Structural Effects on Cu2S2 Bonding and Reactivity in Side-On Disulfido-Bridged Dicopper Complexes.” Inorganic Chemistry 2007, 46, 486-496.
[7] York, J. T.; Young, V. G. Jr.; Tolman, W. B. “Heterobimetallic Activation of Dioxygen: Characterization and Reactivity of Novel Cu(I)-Ge(II) Complexes.” Inorganic Chemistry 2006, 45, 4191-4198.
[8] Aboelella, N. W.; Gherman, B. F.; Hill, L. M. R.; York, J. T.; Holm, N.; Young, V. G. Jr.; Cramer, C. J.; Tolman, W. B. “Effects of Thioether Substituents on the O2 Reactivity of b-Diketiminate-Cu(I) Complexes: Probing the Role of the Methionine Ligand in Copper Monooxygenases.” Journal of the American Chemical Society 2006, 128, 3445-3448.
[9] York, J. T.; Brown, E. C.; Tolman, W. B. “Characterization of a Complex Comprising a [Cu2(S2)2]2+ Core: Bis(m-S22-)dicopper(III) or Bis(m‑S2-•)dicopper(II)?” Angewandte Chemie, International Edition 2005, 44, 7745-7748.
[10] Brown, E. C.; York, J. T.; Antholine, W. E.; Ruiz, E.; Alvarez, S.; Tolman, W. B. “[Cu3(m‑S)2]3+ Clusters Supported by N-Donor Ligands: Progress Towards a Synthetic Model of the Catalytic Site of Nitrous Oxide Reductase.” Journal of the American Chemical Society 2005, 127, 13752-13753.
[11] Aboelella, N. W.; York, J. T.; Reynolds, A. M.; Fujita, K.; Kinsinger, C. R.; Cramer, C. J.; Riordan, C. G.; Tolman, W. B. “Mixed-Metal Bis(m-oxo) Complexes with [CuM(m-O)2]n+ (M = Ni(III) or Pd(II)) Cores.” Chemical Communications 2004, 1716-1717.
[12] York, J. T.; Coalson, R. D.; Dahnovsky, Y. “Control of Electron Current by Double-Barrier Structures Using Pulsed Laser Fields.” Physical Review B. 2002, 65, 235321-235329.
[13] York, J. T.; Dahnovsky, Y. “The Transfer of an Electron Driven by Laser in Electronic Molecular Devices.” Journal of Physical Chemistry B. 2001, 105, 8278-8280.
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